|
ELECTROCHEMISTRY EXPERIMENT 3
OBJECTIVES:
1.) To assemble several representative "wet cells" using
copper, zinc and magnesium electrodes to establish
a hierarchy of reduction potentials (SRPs) for these
metals and their respective metal ion solutions.
2.) To test several experimental electrodes brought in from
home and compare them with the provided electrodes.
3.) To develop a practical mastery of voltaic cells (batteries)
by using various metal electrodes, metal ion solutions,
a salt bridge and a voltmeter.
MATERIALS AND EQUIPMENT:
1.) Each member of your group should bring in a
potential metal electrode (not copper, zinc or magnesium)
from home. Choose from metal objects which you have some
familiarity with and which you think will conduct electricity.
2.) A voltmeter with connecting red and black connecting wires.
3.) Copper, zinc and magnesium electrodes with connecting wires.
4.) Metal ion solutions of copper(II), zinc(II) and magnesium(II).
5.) Salt bridges and potassium nitrate solution.
PROCEDURES:
1.) Using the textbook and/or the CD-ROM Interactive Chapter(20)
assemble the three possible "wet cell" combinations using
copper, zinc and magnesium electrodes, the corresponding metal
ion nitrate salt solutions, a filter paper salt bridge
saturated with potassium nitrate solution and
a voltmeter with red and black connecting wires.
2.) Assemble "wet cells" using your groups' three electrodes
brought in from home. Assemble as few or as many combinations
as necessary using the provided electrodes. Potassium nitrate
should be used as your metal ion solution for each electrode
brought from home.
LAB REPORT 3
(25 POINTS)
Name_________________Section________________Date________________
I. FUNDAMENTALS
A. (3 points) Write the Standard Oxidation Potential(SOP)
half-reaction for each of the provided metal electrodes:
1. copper _____________________________________________
2. zinc______________________________________________
3. magnesium______________________________________________
B. (3 points) Write the Standard Reduction Potential(SRP)
half-reaction for each of the provided metal electrodes:
1. copper ______________________________________________
2. zinc_______________________________________________
3. magnesium_______________________________________________
II. DATA COLLECTION
A. (3 points) List the observed potentials for the three
metals provided:
Anode Metal Cathode Metal Potential(volts)
1. ______________ + ____________________ __________________
2. ______________ + ____________________ __________________
3. ______________ + ____________________ __________________
B. (3 points) Using the potentials above list the SRP
half-reactions for the three metal electrodes provided
in the proper order of reduction (highest SRP to lowest
SRP; most easily reduced to most easily oxidized):
1. _______________________________________________________
2. _______________________________________________________
3. _______________________________________________________
C. (7 points) List the observed potentials for the three
metals you brought from home combined together or with
the three metals provided(restrict choices to seven
combinations):
Anode Metal Cathode Metal Potential(volts)
1. ______________ + ____________________ __________________
2. ______________ + ____________________ __________________
3. ______________ + ____________________ ___________________
4. ______________ + ____________________ ___________________
5. ______________ + ____________________ ___________________
6. ______________ + ____________________ ____________________
7. ______________ + ____________________ ____________________
III. RESULTS
(6 points) Using the potentials above list the SRP
half-reactions for all six metal electrodes
in the proper order of reduction (highest SRP to
lowest SRP; most easily reduced to most easily oxidized):
1. _______________________________________________________
2. _______________________________________________________
3. _______________________________________________________
4. _______________________________________________________
5. _______________________________________________________
6. _______________________________________________________
|